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June : Company develops 'green' graphite from forestry waste

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20 June, 2018

Company develops 'green' graphite from forestry waste

Company develops 'green' graphite from forestry waste
CarbonScape has patented a new 'green' process for manufacturing graphite, from left, head of research
and development Greg Connor, chairman Tim Langley, and chief executive Oliver Foster.

A Marlborough company may have struck gold with its own modern-day philosopher's stone, turning waste sawdust into valuable graphite.

Graphite is considered a 'strategic mineral' by the United States for its use in many applications, such as the significant component of lithium ion batteries.

CarbonScape chief executive Oliver Foster said there was a way to go before commercial production of graphite but producing the amount they had so far had been a significant milestone.

Green graphite
Graphite produced by Carbonscape's patented process, turning forestry waste into carbon and then graphite

More than 1 million tonnes of graphite was mined worldwide in 2016, with the bulk coming from China. 

The majority of synthetic graphite was also produced in China using a high-energy, intensive process using petroleum pitch and tar, taking carbon out of the ground.

CarbonScape head of research and development Greg Conner said producing graphite normally took 11 weeks and temperatures of 2800 degree Celsius.

But the company, based at Riverlands Estate outside Blenheim, had found a way turn sawdust, from the common radiata pine, into graphite through a patented two-step process.

"It's really inefficient. We can do it much quicker," Conner said.

"Graphite is just carbon stacked in a neat, 3D order. Traditionally, you can't change the amorphous form of carbon into graphite.

"[But] using microwaves and our two-step process, we've found a way to convert it really quickly and efficiently.

"It's approaching the quality of the commercial stuff."

CarbonScape's process started with raw sawdust. "Uniquely, we can use it wet. The water participates in the chemical reaction," Conner said.

More water was added and under high pressure, the slurry was microwaved. 

"It's not your conventional microwave oven, it's a microwave reactor.

"The second stage is where the magic happens," Conner said.

The carbon was soaked in a reusable catalyst that activated it, which was then heated until it turned into graphite. 

As the carbon got more pure, it conducted electricity and allowed CarbonScape to achieve the high temperatures necessary to produce graphite.

"We're going from several weeks to a couple of hours," Conner said.

Foster said they were aiming for 99 per cent purity, their product currently sitting around 97 per cent purity.

"Doing it fast and doing it green is our mantra."

But it would be two to three years before they could get their graphite to the market, Foster said.

CarbonScape was originally set up in 2006 to produce green coke for steel plants, the discovery of graphite came through experimentation at high temperatures and research into various catalysts.

The company pivoted from the low-value products, coke and activated carbon, to graphite in 2016.

​Source: Stuff

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